An Integrated CO2 Electrolyzer and Formate Fuel Cell Enabled by a Reversibly Restructuring Pb–Pd Bimetallic Catalyst. (14th February 2019)

• Record Type: Journal Article
• Authors: Lu, Xu; Wu, Yueshen; Yuan, Xiaolei; Wang, Hailiang
• Is Part Of: Angewandte Chemie. Volume 131:Number 12(2019)
• Page Start: 4071
• Page End: 4075
• Publication Date: 2019-02-14
• Subjects: CO2-Reduktion -- Energiespeicherung -- Formiatoxidation -- Pb-Pd-Legierung -- Reversible Restrukturierung; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201814257
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: A single device combining the functions of a CO2 electrolyzer and a formate fuel cell is a new option for carbon‐neutral energy storage but entails rapid, reversible and stable interconversion between CO2 and formate over a single catalyst electrode. We report a new catalyst with such functionalities based on a Pb–Pd alloy system that reversibly restructures its phase, composition, and morphology and thus alters its catalytic properties under controlled electrochemical conditions. Under cathodic conditions, the catalyst is relatively Pb‐rich and is active for CO2 ‐to‐formate conversion over a wide potential range; under anodic conditions, it becomes relatively Pd‐rich and gains stable catalytic activity for formate‐to‐CO2 conversion. The bifunctional activity and superior durability of our Pb–Pd catalyst leads to the first proof‐of‐concept demonstration of an electrochemical cell that can switch between the CO2 electrolyzer/formate fuel cell modes and can stably operate for 12 days. Abstract : Reversibel restrukturiert : Ein Katalysator aus einer Blei‐Palladium‐Legierung verändert reversibel seine Zusammensetzung und Funktion unter elektrochemisch reduzierenden oder oxidierenden Bedingungen. Seine difunktionale Aktivität und überlegene Beständigkeit ermöglichten eine prototypische elektrochemische Baueinheit, die Funktionen eines Kohlendioxid‐Elektrolyseurs und einer Formiatbrennstoffzelle vereint.