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Front Cover: Size‐Exclusion Borane‐Catalyzed Domino 1, 3‐Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1, 3‐Allylic Shift Aptitude (Chem. Eur. J. 9/2019). Issue 9 (25th January 2019)
Record Type:
Journal Article
Title:
Front Cover: Size‐Exclusion Borane‐Catalyzed Domino 1, 3‐Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1, 3‐Allylic Shift Aptitude (Chem. Eur. J. 9/2019). Issue 9 (25th January 2019)
Main Title:
Front Cover: Size‐Exclusion Borane‐Catalyzed Domino 1, 3‐Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1, 3‐Allylic Shift Aptitude (Chem. Eur. J. 9/2019)
Abstract : A reductive Ireland–Claisen reaction was developed utilizing a boron‐based Lewis acid catalyst with size‐exclusion design. In the graphical art, the juggler throws balls up into the air to create the pattern of a catalytic cycle. In addition, the juggler has to wear special gloves with small holes (size‐exclusion) to catch and carry the balls. Large‐hole gloves are inappropriate for this activity because balls would pass straight through and no catalytic reaction would occur. More information can be found in the Communication by T. Soós et al. on page 2179 .