Protic ionic liquid assisted solution processing of lead halide perovskites with water, alcohols and acetonitrile. (September 2018)

• Record Type: Journal Article
• Authors: Öz, Senol; Burschka, Julian; Jung, Eunhwan; Bhattacharjee, Ripon; Fischer, Thomas; Mettenbörger, Andreas; Wang, Hongxia; Mathur, Sanjay
• Is Part Of: Nano energy. Volume 51(2018)
• Page Start: 632
• Page End: 638
• Publication Date: 2018-09
• Subjects: Green solvents -- Protic ionic liquids -- Lead halide perovskite -- Solution processing -- Solar cell; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2018.07.005
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: A major obstacle and persisting challenge towards safe and sustainable industrial scale processing and commercialization of perovskite based (opto)electronic devices including solar cells lies in the essential need of strongly coordinating toxic solvents such as N, N -dimethylformamide (DMF) in the preparation of perovskite precursor inks. In this work, we present novel ink systems for perovskite precursors composed of protic ionic liquids (PILs) based on methylammonium cation and carboxylate anion and their binary blends with water, alcohols and acetonitrile for solution processing of CH3 NH3 PbX3 (X = I, Br). Among the investigated ink-systems, new PIL methylammonium propionate and its blends were identified as the most promising candidates in terms of chemical stability and compatibility for single- and two-step solution processing of the perovskite materials. Multi-cation mixed halide perovskites solar cells prepared with PIL/acetonitrile solvent system showed power conversion efficiency in excess of 15%. Graphical abstract: fx1 Highlights: Methylammonium propionate a new stable room temperature protic ionic liquid is presented. New binary hybrid perovskite ink systems with water, ethanol, isopropanol and acetonitrile as (co)-solvents are presented. Ink-jet printing of CH3 NH3 PbI3 was demonstrated using methylammonium propionate/water based perovskite inks. MAP/DMSO/acetonitrile solvent system was applied for sequential deposition of (MA0.15 FA0.85 )Pb(I0.85 Br0.15 )3 thin films.