The effect of several activated biochars on Cd immobilization and microbial community composition during in-situ remediation of heavy metal contaminated sediment. (October 2018)

• Record Type: Journal Article
• Authors: Liu, Si-jia; Liu, Yun-guo; Tan, Xiao-fei; Zeng, Guang-ming; Zhou, Ya-hui; Liu, Shao-bo; Yin, Zhi-hong; Jiang, Lu-hua; Li, Mei-fang; Wen, Jun
• Is Part Of: Chemosphere. Volume 208(2018)
• Page Start: 655
• Page End: 664
• Publication Date: 2018-10
• Subjects: Sediment -- In-situ remediation -- Activated biochar -- Cadmium -- Microbial community composition; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2018.06.023
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Chemical activation and microwave assisted activation were adopted to modify biochar. Activated biochars were characterized by SEM, BET, FTIR, XRD and XPS. Raw biochar, activated biochars and commercial activated carbon were compared as remediation strategies for sediment from the Xiangjiang River containing 14.70 mg/kg Cd. After the treatment by activated biochar, the overlying water and pore water concentration of Cd decreased by 71% and 49%, respectively. And the threat of heavy metal along with bioavailability of Cd was depressed. Moreover, the immobilsation of Cd in sediment was related to BET surface area and the content of oxygen containing functional groups of activated biochars. Furthermore, a PCR-DGGE-based experiment was performed for the detection of microbial community. The indigenous microbial community was affected and new microbial community appeared after treat by activated biochar. Activated biochar can be used as an inexpensive and efficient in situ remediation material of sediment containing metal. Graphical abstract: Image 1 Highlights: Activated biochar addition decreased the aqueous concentrations of Cd in sediment. Activated biochar showed excellent performance in immobilization of Cd in sediment. Activated biochar improved the pH and the CEC of sediment. Activated biochar influenced bacterial community diversity.