Catalytic C−C Bond Formation Using a Simple Nickel Precatalyst System: Base‐ and Activator‐Free Direct C‐Allylation by Alcohols and Amines. Issue 29 (27th April 2018)

• Record Type: Journal Article
• Authors: Sweeney, Joseph B.; Ball, Anthony K.; Smith, Luke J.
• Is Part Of: Chemistry. Volume 24:Issue 29(2018)
• Page Start: 7354
• Page End: 7357
• Publication Date: 2018-04-27
• Subjects: allylation -- C−C bond formation -- nickel -- quaternary -- sustainable chemistry; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201801241
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: A "totally catalytic" nickel(0)‐mediated method for base‐free direct alkylation of allyl alcohols and allyl amines is reported. The reaction is selective for monoallylation, uses an inexpensive Ni II precatalyst system, and requires no activating reagents to be present. Abstract : A "totally catalytic" nickel(0)‐mediated method for base‐free direct alkylation of allyl alcohols and allyl amines is reported. The reaction is selective for monoallylation, uses an inexpensive Ni II precatalyst system, and requires no activating reagents to be present.