Rhodium(III)‐Catalyzed Annulation of 2‐Alkenyl Anilides with Alkynes through C−H Activation: Direct Access to 2‐Substituted Indolines. (4th June 2018)
- Record Type:
- Journal Article
- Title:
- Rhodium(III)‐Catalyzed Annulation of 2‐Alkenyl Anilides with Alkynes through C−H Activation: Direct Access to 2‐Substituted Indolines. (4th June 2018)
- Main Title:
- Rhodium(III)‐Catalyzed Annulation of 2‐Alkenyl Anilides with Alkynes through C−H Activation: Direct Access to 2‐Substituted Indolines
- Authors:
- Font, Marc
Cendón, Borja
Seoane, Andrés
Mascareñas, José Luis
Gulías, Moisés - Abstract:
- Abstract: A Rh III complex featuring an electron‐deficient η 5 ‐cyclopentadienyl ligand catalyzed an unusual annulation between alkynes and 2‐alkenyl anilides to form synthetically appealing 2‐substituted indolines. Formally, the process can be viewed as an allylic amination with concomitant hydrocarbonation of the alkyne. Mechanistic experiments indicate that this transformation involves an unusual rhodium migration with a concomitant 1, 5‐H shift.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 27(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 27(2018)
- Issue Display:
- Volume 130, Issue 27 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 27
- Issue Sort Value:
- 2018-0130-0027-0000
- Page Start:
- 8387
- Page End:
- 8391
- Publication Date:
- 2018-06-04
- Subjects:
- Anellierungen -- C-H-Aktivierung -- Indoline -- Rhodium -- Rhodium-Verschiebung
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201802830 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 12376.xml