Development of an Alkyne Analogue of the de Mayo Reaction: Synthesis of Medium‐Sized Carbacycles and Cyclohepta[b]indoles. (30th October 2018)
- Record Type:
- Journal Article
- Title:
- Development of an Alkyne Analogue of the de Mayo Reaction: Synthesis of Medium‐Sized Carbacycles and Cyclohepta[b]indoles. (30th October 2018)
- Main Title:
- Development of an Alkyne Analogue of the de Mayo Reaction: Synthesis of Medium‐Sized Carbacycles and Cyclohepta[b]indoles
- Authors:
- Tymann, David
Tymann, Dina Christina
Bednarzick, Ulf
Iovkova‐Berends, Ljuba
Rehbein, Julia
Hiersemann, Martin - Abstract:
- Abstract: Embedded medium‐sized carbacycles and cyclohepta[b]indoles occur frequently as scaffold elements in natural products and bioactive compounds. Described herein is a conceptionally novel photochemically triggered cascade process to these scaffolds. Key to the cascading ring‐expansion process is an unprecedented intramolecular alkyne analogue of the de Mayo reaction.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 47(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 47(2018)
- Issue Display:
- Volume 130, Issue 47 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 47
- Issue Sort Value:
- 2018-0130-0047-0000
- Page Start:
- 15779
- Page End:
- 15783
- Publication Date:
- 2018-10-30
- Subjects:
- Cycloadditionen -- Heterocyclen -- Photochemie -- Radikale -- Reaktionsmechanismen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201808578 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 12376.xml