Bismuth nitrate as a source of nitro radical in ipso-nitration of carboxylic acids. (1st November 2019)

• Record Type: Journal Article
• Authors: Agasti, Soumitra; Maiti, Siddhartha; Maity, Soham; Anniyappan, M.; Talawar, M.B.; Maiti, Debabrata
• Is Part Of: Polyhedron. Volume 172(2019)
• Page Start: 120
• Page End: 124
• Publication Date: 2019-11-01
• Subjects: Nitration -- Nitro -- Radical -- Decarboxylation -- Bismuth; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2019.04.005
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical abstract: Aromatic nitro compounds are extensively used in synthetic chemistry. We disclose a new approach to obtain nitroarenes regioselectively starting from carboxylic acids under acid-free reaction conditions. Abstract: Aromatic nitro compounds are extensively used in synthetic chemistry. We disclose a new approach to obtain nitroarenes regioselectively starting from carboxylic acids under acid-free reaction conditions.