Continuous Visible‐Light Photoflow Approach for a Manganese‐Catalyzed (Het)Arene C−H Arylation. Issue 33 (3rd July 2018)

• Record Type: Journal Article
• Authors: Liang, Yu‐Feng; Steinbock, Ralf; Yang, Long; Ackermann, Lutz
• Is Part Of: Angewandte Chemie international edition. Volume 57:Issue 33(2018)
• Page Start: 10625
• Page End: 10629
• Publication Date: 2018-07-03
• Subjects: C−H arylations -- continuous photoflow reactions -- manganese -- photocatalysis -- visible light; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201805644
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Manganese photocatalysts enabled versatile room‐temperature C−H arylation reactions by means of continuous visible‐light photoflow, thus allowing for efficient C−H arylations in 30 minutes with ample scope. The robustness of the manganese‐catalyzed photoflow strategy was shown by visible light‐induced gram‐scale synthesis, clearly outperforming the batch performance. Abstract : Photochemistry in the flow : Earth‐abundant manganese catalysts enabled visible‐light‐induced C−H arylations at room temperature in a continuous photoflow manifold.