Copper‐Catalyzed Radical Cross‐Coupling of Redox‐Active Oxime Esters, Styrenes, and Boronic Acids. (19th October 2018)
- Record Type:
- Journal Article
- Title:
- Copper‐Catalyzed Radical Cross‐Coupling of Redox‐Active Oxime Esters, Styrenes, and Boronic Acids. (19th October 2018)
- Main Title:
- Copper‐Catalyzed Radical Cross‐Coupling of Redox‐Active Oxime Esters, Styrenes, and Boronic Acids
- Authors:
- Yu, Xiao‐Ye
Zhao, Quan‐Qing
Chen, Jun
Chen, Jia‐Rong
Xiao, Wen‐Jing - Abstract:
- Abstract: A visible‐light‐driven, copper‐catalyzed three‐component radical cross‐coupling of oxime esters, styrenes, and boronic acids has been developed. Key steps of this protocol involve catalytic generation of an iminyl radical from a redox‐active oxime ester and subsequent C−C bond cleavage to generate a cyanoalkyl radical. Upon its addition to styrene, the newly formed benzylic radical undergoes coupling with a boronic‐acid‐derived ArCu II complex to achieve 1, 1‐diarylmethane‐containing alkylnitriles.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 47(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 47(2018)
- Issue Display:
- Volume 130, Issue 47 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 47
- Issue Sort Value:
- 2018-0130-0047-0000
- Page Start:
- 15731
- Page End:
- 15735
- Publication Date:
- 2018-10-19
- Subjects:
- Kreuzkupplungen -- Kupfer -- Photochemie -- Radikale -- Synthesemethoden
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201809820 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 12290.xml