Visible Light‐Driven, Photocatalyst‐Free Arbuzov‐Like Reaction via Arylazo Sulfones. Issue 22 (7th October 2019)

• Record Type: Journal Article
• Authors: Qiu, Di; Lian, Chang; Mao, Jinshan; Ding, Yi; Liu, Zerong; Wei, Liyan; Fagnoni, Maurizio; Protti, Stefano
• Is Part Of: Advanced synthesis & catalysis. Volume 361:Issue 22(2019)
• Page Start: 5239
• Page End: 5244
• Publication Date: 2019-10-07
• Subjects: Arylazo Sulfones -- Photocatalyst-Free Reactions -- Aryl Radical -- Arbuzov Reaction -- Photochemistry; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201900953
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: A visible light‐induced formation of Aryl‐Phosphorous bonds starting from arylazo sulfones and triaryl (or trialkyl)phosphites in the absence of any photoredox catalyst and any additives was developed. This reaction showed a broad substrate scope and afforded (hetero)aryl phosphonates in good yields and in up to the gram scale. Abstract :