Direct synthesis of dialkylarylvinylsilane derivatives: metathesis of dialkylaryl-iso-propenylsilane and its application to tetracyclic silacycle dye synthesis. Issue 93 (7th November 2019)

• Record Type: Journal Article
• Authors: Yoshioka, Shohei; Takehara, Tsunayoshi; Matsuzaki, Tsuyoshi; Suzuki, Takeyuki; Tsujino, Hirofumi; Uno, Tadayuki; Tsutsumi, Yasuo; Murai, Kenichi; Fujioka, Hiromichi; Arisawa, Mitsuhiro
• Is Part Of: Chemical communications. Volume 55:Issue 93(2019)
• Page Start: 14070
• Page End: 14073
• Publication Date: 2019-11-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc06777a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The metathesis of dialkylarylvinylsilane, which has not been accomplished to date, is achieved using dialkylaryl-iso-propenylsilane as a substrate. Abstract : The metathesis of dialkylarylvinylsilane, which has not been accomplished to date, is achieved using dialkylaryl-iso-propenylsilane as a substrate. In addition, we discovered that the reason why the metathesis of a ruthenium carbene complex and dialkylarylvinylsilane is difficult is the formation of a carbide complex.