Facile synthesis of silver alkynide cluster and coordination polymers using picolinic acid as a co-ligand. Issue 44 (30th October 2019)

• Record Type: Journal Article
• Authors: Gupta, Arvind Kumar; Orthaber, Andreas
• Is Part Of: Dalton transactions. Volume 48:Issue 44(2019)
• Page Start: 16518
• Page End: 16524
• Publication Date: 2019-10-30
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt03697k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : We describe five 1D-coordination polymers and two discrete silver clusters consisting of alkynides and picolinic carboxylates as co-ligands. Abstract : We describe five 1D-coordination polymers and two discrete silver clusters consisting of alkynides and picolinic carboxylates as co-ligands. In some cases, DMSO or EtOH further solvated the structural motifs. Utilising the sterically demanding tri-isopropylsilyl acetylene afforded a tridecanuclear cluster that possessed an unprecedented core with a silver center surrounded by six octahedrally arranged silver atoms.