Unprecedented five-fold interpenetrated donor–acceptor hybrid heterostructure induced by anion–π interactions. Issue 44 (21st October 2019)

• Record Type: Journal Article
• Authors: You, Ming-Hua; Li, Meng-Hua; Liu, Yong-Fei; Li, Hao-Hong; Lin, Mei-Jin
• Is Part Of: CrystEngComm. Volume 21:Issue 44(2019)
• Page Start: 6688
• Page End: 6692
• Publication Date: 2019-10-21
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c9ce01416k
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : An unprecedented five-fold interpenetrated D–A hybrid heterostructural complex has been constructed, wherein anion–π interactions play a key role in its interpenetration and photoinduced electron transfers. Abstract : The combination of hexacyanoferrate anions with protonated N, N ′-dipyridyl-naphthalene diimide tectons resulted in a novel cuboid 3-D H-bonded anion-coordinated framework. Induced by anion–π interactions, such a unique framework is further catenated into an unprecedented five-fold interpenetrated D–A hybrid heterostructure with 1-D hexacyanoferrate polyanions and naphthalene diimide aggregates as electron donors and acceptors, respectively. The photophysical and photochemical properties have also been discussed.