Cu(i)–SNS complexes for outer-sphere hydroboration and hydrosilylation of carbonyls. Issue 90 (28th October 2019)
- Record Type:
- Journal Article
- Title:
- Cu(i)–SNS complexes for outer-sphere hydroboration and hydrosilylation of carbonyls. Issue 90 (28th October 2019)
- Main Title:
- Cu(i)–SNS complexes for outer-sphere hydroboration and hydrosilylation of carbonyls
- Authors:
- Elsby, Matthew R.
Baker, R. Tom - Abstract:
- Abstract : Two new NHC–Cu(i )-[κ 2 -SNS] complexes were synthesized to directly compare the bifunctional catalytic activity of a hard amido vs. a soft thiolate donor. Abstract : Two new NHC–Cu(i )-[κ 2 -SNS] complexes were synthesized to directly compare the bifunctional catalytic activity of a hard amido vs. a soft thiolate donor. The Cu thiolate complex catalyzed ketone hydroboration but not hydrosilylation, while the Cu amido complex is a high-performing outer-sphere carbonyl reduction catalyst using boranes and silanes.
- Is Part Of:
- Chemical communications. Volume 55:Issue 90(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 90(2019)
- Issue Display:
- Volume 55, Issue 90 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 90
- Issue Sort Value:
- 2019-0055-0090-0000
- Page Start:
- 13574
- Page End:
- 13577
- Publication Date:
- 2019-10-28
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc07266g ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 12104.xml