Strong and Tunable Electrical Anisotropy in Type‐II Weyl Semimetal Candidate WP2 with Broken Inversion Symmetry. Issue 44 (18th September 2019)

• Record Type: Journal Article
• Authors: Su, Bo; Song, Yanpeng; Hou, Yanhui; Chen, Xu; Zhao, Jianzhou; Ma, Yongchang; Yang, Yang; Guo, Jiangang; Luo, Jianlin; Chen, Zhi‐Guo
• Is Part Of: Advanced materials. Volume 31:Issue 44(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-09-18
• Subjects: first‐principle calculations -- in‐plane electrical anisotropy -- optical spectroscopy -- Raman spectroscopy -- type‐II Weyl semimetal; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201903498
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: A transition metal diphosphide, WP2, is a candidate for type‐II Weyl semimetals (WSMs) in which spatial inversion symmetry is broken and Lorentz invariance is violated. As one of the prerequisites for the presence of the WSM state in WP2, spatial inversion symmetry breaking in this compound has rarely been investigated. Furthermore, the anisotropy of the WP2 electrical properties and whether its electrical anisotropy can be tuned remain elusive. Angle‐resolved polarized Raman spectroscopy, electrical transport, optical spectroscopy, and first‐principle studies of WP2 are reported. The energies of the observed Raman‐active phonons and the angle dependences of the detected phonon intensities are consistent with results obtained by first‐principle calculations and analysis of the proposed crystal symmetry without spatial inversion, showing that spatial inversion symmetry is broken in WP2 . Moreover, the measured ratio ( Rc / Ra ) between the crystalline c ‐axis and a ‐axis electrical resistivities exhibits a weak dependence on temperature ( T ) in the temperature range from 100 to 250 K, but increases abruptly at T ≤ 100 K, and then reaches the value of ≈8.0 at T = 10 K, which is by far the strongest in‐plane electrical resistivity anisotropy among the reported type‐II WSM candidates with comparable carrier concentrations. Optical spectroscopy study, together with the first‐principle calculations on the electronic band structure, reveals that the abrupt enhancement of the electrical resistivity anisotropy at T ≤ 100 K mainly arises from a sharp increase in the scattering rate anisotropy at low temperatures. More interestingly, the Rc / Ra of WP2 at T = 10 K can be tuned from 8.0 to 10.6 as the magnetic field increases from 0 to 9 T. The so‐far‐strongest and magnetic‐field‐tunable electrical resistivity anisotropy found in WP2 can serve as a degree of freedom for tuning the electrical properties of type‐II WSMs, which paves the way for the development of novel electronic applications based on type‐II WSMs. Abstract : The transition‐metal diphosphide WP2 is a type‐II Weyl semimetal candidate. The anisotropy of its ac ‐plane resistivity, which mainly arises from the scattering rate anisotropy, increases sharply at temperature T ≤ 100 K without phase transitions and can be tuned by magnetic fields. The broken inversion symmetry in WP2 is identified by combining linearly polarized Raman spectroscopy and first‐principle calculations.