PIDA‐Promoted Selective C5 C−H Selenylations of Indolines via Weak Interactions. Issue 21 (12th September 2019)

• Record Type: Journal Article
• Authors: Gu, Linghui; Fang, Xinyue; Weng, Zhengyun; Lin, Jiafu; He, Meicui; Ma, Wenbo
• Is Part Of: Advanced synthesis & catalysis. Volume 361:Issue 21(2019)
• Page Start: 4998
• Page End: 5004
• Publication Date: 2019-09-12
• Subjects: PIDA -- Selenylations -- Indoline -- C−H functionalization -- Radical reactions; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201900766
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: An efficient PIDA (phenyliodine(III) diacetate)‐promoted positional selective C−H selenylations of indolines with diaryl diselenides has been developed. This transformation conducted under mild reaction conditions with a broad functional group tolerance, thus providing an efficient protocol to selenylated indolines. Preliminary mechanistic studies indicated a SET pathway was likely involved in this selenylation reaction. Abstract :