Photophysics and electroluminescence of red quantum dots diluted in a thermally activated delayed fluorescence host. Issue 42 (14th October 2019)

• Record Type: Journal Article
• Authors: Xiang, Yepeng; Xie, Guohua; Huang, Manli; Yang, Chuluo
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 42(2019)
• Page Start: 13218
• Page End: 13223
• Publication Date: 2019-10-14
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c9tc04340c
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : By simply mixing organic host material and quantum dots to form an emitting layer, highly efficient red QLEDs without a hole transport layer were achieved. The benchmark device based on the dendrimer host material reached a peak EQE of 11.9%. Abstract : A feasible, universal, and low-cost strategy for quantum dot light-emitting devices (QLEDs) was provided to significantly enhance the electroluminescent performances. The emissive layer consists of organic host materials and quantum dots (QDs), and then the efficient energy transfer process remarkably promotes the device performances. It is confirmed that a highly efficient QLED can be realized by a host–guest system without common hole transport layers. The red device based on the thermally activated delayed fluorescence host and QD guest achieved a peak external quantum efficiency of 7.4%. Further, by simply modifying PEDOT:PSS with poly(4-styrenesulfonic acid), the work-function can be easily elevated, accompanied with the boosted external quantum efficiency to 11.9%. It is believed that such performances originate simultaneously from reduced interfacial fluorescence quenching, elevated work-function and efficient Förster resonance energy transfer in the host–guest system.