Calcination of calcium sulphoaluminate cement using flue gas desulfurization gypsum as whole calcium oxide source. (20th December 2019)

• Record Type: Journal Article
• Authors: Wu, Shuang; Wang, Wenlong; Ren, Changzai; Yao, Xingliang; Yao, Yonggang; Zhang, Qingsong; Li, Zhaofeng
• Is Part Of: Construction & building materials. Volume 228(2019)
• Publication Date: 2019-12-20
• Subjects: Flue gas desulfurization gypsum -- Calcium sulphoaluminate cement -- Decomposition -- Clinker phases -- Mechanical property; Building materials -- Periodicals; 624.18
• DOI: 10.1016/j.conbuildmat.2019.116676
• Languages: English
• ISSNs: 0950-0618

Abstract

Highlights: Innovative preparation of CSA cement entirely with FGD gypsum providing the CaO. Decomposition characteristics of FGD gypsum in CSA clinker preparation were elaborated. Properties of CSA cement made from FGD gypsum were investigated. Abstract: Flue gas desulfurization (FGD) gypsum is an industrial by-product of the desulfurization process. The gross product of FGD gypsum has reached 550 million tons in China by 2016 and quite a portion was discarded. The purpose of this study is to investigate the feasibility of an innovative concept of producing the CSA cement based on sulfur recovery and entirely made of the FGD gypsum to replace natural gypsum and limestone as CaO and SO3 sources. A mixture of industrial solid waste was calcined under different calcination conditions to study the decomposition behavior of FGD gypsum and properties of CSA cement made from the FGD gypsum. Experimental results show that it is feasible to use the FGD gypsum to entirely supply the CaO and SO3 of this cement, the optimized calcination temperature is between 1270 and 1310 °C, and the suitable retention time is 60–100 min. The highest compressive strengths of 63.3, 85.3, 102.8 MPa were attained at 1, 3, and 28 d, respectively when the temperature was kept at 1310 °C for 60 min. Results also indicate that the FGD gypsum decomposition, which is mainly influenced by calcination temperature, retention time and alumina–silica ratio, has a significant impact on the clinker mineral phase formation. The novel technical idea developed in this research can greatly improve the utilization of FGD gypsum and may reduce about 50% of CO2 emission in routine production.