Thermo-mechanical and photo-luminescence properties of micro-actuators made of liquid crystal elastomers with cyano-oligo(p-phenylene vinylene) crosslinking bridges. (1st October 2019)

• Record Type: Journal Article
• Authors: Ni, Bin; Chen, Hui; Zhang, Mengxue; Keller, Patrick; Tatoulian, Michael; Li, Min-Hui
• Is Part Of: Materials chemistry frontiers. Volume 3:Number 11(2019)
• Page Start: 2499
• Page End: 2506
• Publication Date: 2019-10-01
• Subjects: Materials science -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1039/c9qm00480g
• Languages: English
• ISSNs: 2052-1529

Abstract

Abstract : Liquid crystal elastomer micropillars containing β-cyano-OPV crosslinkers contract reversibly at nematic–isotropic (N–I) phase transition and undergo fluorescence intensity change. This luminescent variation is mainly caused by N–I phase change. Abstract : Nematic liquid crystal elastomer (LCE) micropillars with reversible thermomechanical deformations and photo luminescence (PL) intensity variations were successfully fabricated by introducing a cyano-oligo( p -phenylene vinylene) dye as a chemical crosslinker. The PL intensity of the micropillars decreased and increased reversibly during the thermal-deformation process. We studied in detail the possible factors that influence the PL intensity variations of the micropillars, including temperature variation, contraction/extension and phase transition. The dye molecules mainly kept the "monomer" state in the micropillars during the thermo-activated deformation. It was found that the phase transition from nematic to isotropic of the LCEs played the major role in the PL intensity variations. This kind of micropillar may have potential application in fluorescent soft sensors and actuators.