Isostructural iron(iii) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties. Issue 41 (17th April 2019)

• Record Type: Journal Article
• Authors: Dankhoff, Katja; Weber, Birgit
• Is Part Of: Dalton transactions. Volume 48:Issue 41(2019)
• Page Start: 15376
• Page End: 15380
• Publication Date: 2019-04-17
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt00846b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Two isostructural iron(iii ) spin crossover complexes show anion-size dependent spin crossover. Abstract : Here we present two isostructural iron(iii ) spin crossover complexes with the same tridentate ligand and perchlorate or tetrafluoroborate as counter ion. Single crystal X-ray structures in the high spin and low spin state were obtained for both complexes. An abrupt spin transition above 100 K is observed with the transition temperature depending on the size of the anion.