Effect of morphology of CsPbBr3 nanocrystals on their optical properties. (16th October 2019)

• Record Type: Journal Article
• Authors: Wu, Haizhen; Mo, Zhaojun; Lu, Qiujie; Li, Hailin; Zheng, Zhexuan; Li, Lan
• Is Part Of: Materials research express. Volume 6:Number 11(2019)
• Publication Date: 2019-10-16
• Subjects: CsPbBr3 nanocrystals -- morphological transformation -- crystal phase conversion -- optical properties; Materials science -- Research -- Periodicals; Materials science -- Periodicals; 620.11
• DOI: 10.1088/2053-1591/ab49ef
• Languages: English
• ISSNs: 2053-1591

Abstract

Abstract: In this paper, the morphology of CsPbBr3 nanocrystals (NCs) is controlled by changing the molar ratios of oleylamine (OAm) and propionic acid (PA). The relative ratio plays an important role in the evolution of morphology. The CsPbBr3 NCs exhibit monoclinic morphology when the molar ratio of OAm/PA is equivalent. When the molar ratio of OAm/PA deviates from 1:1, CsPbBr3 NCs tend to grow in a sheet shape. The nanosheets with 200∼500 nm and thickness ∼15 nm were synthesized as the molar ratio of OAm/PA (1:4). The PL intensity decreases with the increase of size. The fluorescence lifetime shows a trend of gradual shortening.