CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation. Issue 39 (13th September 2019)

• Record Type: Journal Article
• Authors: Kumar, Amit; Daw, Prosenjit; Espinosa-Jalapa, Noel Angel; Leitus, Gregory; Shimon, Linda J. W.; Ben-David, Yehoshoa; Milstein, David
• Is Part Of: Dalton transactions. Volume 48:Issue 39(2019)
• Page Start: 14580
• Page End: 14584
• Publication Date: 2019-09-13
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt03088c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Activation of CO2 by manganese pincer complexes using two different modes of metal–ligand cooperativity (amido/amino mode and dearomatization/aromatization mode) is reported. Abstract : We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1, 2]-activation of CO2 and dearomatization/aromatization mode that involves [1, 3]-activation of CO2 . We also compare their catalytic activity for CO2 hydrogenation.