Trinuclear Ni(ii) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation. Issue 39 (24th September 2019)

• Record Type: Journal Article
• Authors: Zhai, Zhi-Min; Yang, Xiao-Gang; Yang, Zhao-Tong; Lu, Xiao-Min; Ma, Lu-Fang
• Is Part Of: CrystEngComm. Volume 21:Issue 39(2019)
• Page Start: 5862
• Page End: 5866
• Publication Date: 2019-09-24
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c9ce00944b
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Trinuclear nickel cluster based MOF shows highly denser crystal packing and π-conjugation degree as well as outstanding OER performance with an overpotential of 270 mV at 10 mA cm −2 . Abstract : Oriented by the structure-directing effect of metal clusters, a novel trinuclear nickel-based MOF (Ni–BTC) exhibited highly denser crystal packing and π-conjugation degree, providing a platform for efficient charge carrier mobility between metal clusters through π-conjugated molecular bridges and long-term stability of an efficient oxygen evolution reaction.