Dynamic visualization of the phase transformation path in LiFePO4 during delithiation. Issue 38 (20th September 2019)

• Record Type: Journal Article
• Authors: Yang, Liting; You, Wenbin; Zhao, Xuebing; Guo, Huiqiao; Li, Xiao; Zhang, Jie; Wang, Yonggang; Che, Renchao
• Is Part Of: Nanoscale. Volume 11:Issue 38(2019)
• Page Start: 17557
• Page End: 17562
• Publication Date: 2019-09-20
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c9nr05623h
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : The delithiation process of LiFePO4 is observed directly by in situ transmission electron microscopy. Abstract : Rechargeable lithium-ion batteries have been widely used in portable electronic devices and electric vehicles over the last few decades. The electrochemical performance of lithium-ion batteries is mostly determined using electrode materials, which allow Li to insert/extract in their crystal structure. Conventionally, high-rate electrode materials store Li + via a solid-state reaction ( i.e., the single-phase transformation path), and one exception is LiFePO4 (LFP). Although its two-phase transformation path has been widely demonstrated, the abnormal correlation between the lithiation/delithiation mechanism and the high rate performance of LFP is still controversial. Recently, the theory has suggested that the single-phase transformation path at a very low overpotential might be responsible for the abnormal phenomenon. However, direct observation of such a single-phase transformation has been rarely achieved, because once the overpotential is removed, the intermediate solid-solution phase Li x FePO4 (0 < x < 1) should separate into thermodynamic LFP and FePO4 (FP). Here, the detailed delithiation path of LFP is directly observed using in situ transmission electron microscopy (TEM) based on a micro-sized solid-state battery (Pt/Li6.4 La3 Zr1.4 Ta6 O12 /LFP). We first demonstrate a novel two-step solid-solution transformation path during the delithiation of LFP, showing direct evidence for the above assumption. These results provide a new insight into the solid-solution transformation mechanism of electrode materials.