Construction of a short metallofullerene-peapod with a spin probe. Issue 77 (6th September 2019)

• Record Type: Journal Article
• Authors: Zhao, Chong; Meng, Haibing; Nie, Mingzhe; Huang, Qiang; Du, Pingwu; Wang, Chunru; Wang, Taishan
• Is Part Of: Chemical communications. Volume 55:Issue 77(2019)
• Page Start: 11511
• Page End: 11514
• Publication Date: 2019-09-06
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc05220h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A short metallofullerene-peapod of Y2 @C79 N⊂[4]CHBC was constructed with a distinct structure and typical spin character. Abstract : A short metallofullere-peapod of Y2 @C79 N⊂[4]CHBC was constructed. The strong confinement effect from the large π-extended [4]CHBC nanoring induces molecular orientation of the wrapped Y2 @C79 N, which can be sensed by a Y2 @C79 N spin probe. The low susceptibility of the spin phase memory time ( T m ) for the Y2 @C79 N spin was also found in a confined space.