Unravelling the spatial dependency of the complex solid-state chemistry of Pb in a paint micro-sample from Rembrandt's Homer using XRD-CT. Issue 13 (25th January 2019)

• Record Type: Journal Article
• Authors: Price, Stephen W. T.; Van Loon, Annelies; Keune, Katrien; Parsons, Aaron D.; Murray, Claire; Beale, Andrew M.; Mosselmans, J. Fred W.
• Is Part Of: Chemical communications. Volume 55:Issue 13(2019)
• Page Start: 1931
• Page End: 1934
• Publication Date: 2019-01-25
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc09705d
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : X-ray diffraction computed tomography (XRD-CT) has been used to identify the nature of crystalline surface deposits in Rembrandt's Homer. Abstract : The surface of many Old Master paintings has been affected by the appearance of whitish lead-rich deposits, which are often difficult to fully characterise, thereby hindering conservation. A paint micro-sample from Rembrandt's Homer was imaged using X-ray Diffraction Computed Tomography (XRD-CT) in order to understand the evolving solid-state Pb chemistry from the painting surface and beneath. The surface crust was identified as a complex mixture of lead sulfates. From the S : Pb ratios throughout the paint layer, we can conclude that S is from an external source in the form of SO2, and that the nature of Pb–SO4 product is dependent on the degree of diffusion/absorption of SO2 into the paint layers.