Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene–Copper Complex. (27th March 2019)
- Record Type:
- Journal Article
- Title:
- Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene–Copper Complex. (27th March 2019)
- Main Title:
- Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene–Copper Complex
- Authors:
- Huang, Yuan
Brown, M. Kevin - Abstract:
- Abstract: The development of pyridylidene‐Cu‐complexes and their application in Cu/Pd‐catalyzed heteroarylboration of alkenylheteroarenes is reported. The significance of 1, 1′‐heteroarylalkanes as building blocks for drug discovery, as well as the straightforward and modular sequence to prepare the pyridylidene‐Cu‐complexes, makes this catalyst and it applications attractive for chemical synthesis. Furthermore, chiral variants of the pyridylidene‐Cu‐complexes have been prepared and utilized in the enantioselective arylboration of E‐alkenes, further demonstrating the value and potential of this class of catalysts.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 18(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 18(2019)
- Issue Display:
- Volume 131, Issue 18 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 18
- Issue Sort Value:
- 2019-0131-0018-0000
- Page Start:
- 6109
- Page End:
- 6113
- Publication Date:
- 2019-03-27
- Subjects:
- Bor -- Heteroarylborierungen -- Heterocyclen -- Kupfer -- Pyridylidene
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201902238 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11954.xml