[2](1, 3)Adamantano[2](2, 7)pyrenophane: A Hydrocarbon with a Large Dipole Moment. (1st July 2016)

• Record Type: Journal Article
• Authors: Kahl, Paul; Wagner, J. Philipp; Balestrieri, Ciro; Becker, Jonathan; Hausmann, Heike; Bodwell, Graham J.; Schreiner, Peter R.
• Is Part Of: Angewandte Chemie. Volume 128:Number 32(2016)
• Page Start: 9423
• Page End: 9427
• Publication Date: 2016-07-01
• Subjects: Allotropie -- Gespannte Moleküle -- Graphen -- Materialwissenschaften -- Strukturaufklärung; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201602201
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: The fusion of the sp 3 ‐hybridized parent diamondoid adamantane with the sp 2 ‐hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.