Structural transformation and electrochemical study of layered MnO2 in rechargeable aqueous zinc-ion battery. (20th June 2018)

• Record Type: Journal Article
• Authors: Alfaruqi, Muhammad Hilmy; Islam, Saiful; Putro, Dimas Yunianto; Mathew, Vinod; Kim, Sungjin; Jo, Jeonggeun; Kim, Seokhun; Sun, Yang-Kook; Kim, Kwangho; Kim, Jaekook
• Is Part Of: Electrochimica acta. Volume 276(2018)
• Page Start: 1
• Page End: 11
• Publication Date: 2018-06-20
• Subjects: Layered manganese dioxide -- Zinc-ion battery -- In situ diffraction; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2018.04.139
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: Layered MnO2 is very attractive cathode material for zinc-ion battery (ZIB) due to its large interlayer distance, high discharge capacity, low cost, and environmental benignity. However, layered MnO2 exhibits capacity fading. Therefore, detailed studies of the structural transformation and electrochemical mechanism of layered MnO2 during cycling are urgently required for performance improvement. In this contribution, we have utilized in situ synchrotron, ex situ X-ray diffraction, and ex situ synchrotron X-ray absorption spectroscopy analyses in order to evaluate the structural transformation of a layered MnO2 during Zn-ion insertion. We found that during initial cycles, the electrode was able to maintain its layered structure; however, after prolonged cycles, it completely transformed into an irreversible spinel structure. We also observed the manganese dissolution from the electrode into the electrolyte during continuous cycling. The formation of irreversible spinel phase and manganese dissolution are responsible for capacity fading. Our findings provide the understanding for further improvement of layered MnO2 as cathode material for next generation ZIB systems. Graphical abstract: Image 1 Highlights: Structural transformation of layered MnO2 during Zn-ion insertion is investigated. During initial cycles, layered MnO2 electrode is able to maintain its structure. Layered MnO2 electrode transforms into spinel structure after prolonged cycles. Spinel formation and manganese dissolution are responsible for capacity loss.