Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine. (25th September 2019)

• Record Type: Journal Article
• Authors: Boutin, Etienne; Wang, Min; Lin, John C.; Mesnage, Matthieu; Mendoza, Daniela; Lassalle‐Kaiser, Benedikt; Hahn, Christopher; Jaramillo, Thomas F.; Robert, Marc
• Is Part Of: Angewandte Chemie. Volume 131:Number 45(2019)
• Page Start: 16318
• Page End: 16322
• Publication Date: 2019-09-25
• Subjects: Cobaltphthalocyanin -- Elektrochemie -- Kohlenmonoxid-Reduktion -- Methanol -- Molekulare Katalysatoren; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201909257
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Conversion of CO2 into valuable molecules is a field of intensive investigation with the aim of developing scalable technologies for making fuels using renewable energy sources. While electrochemical reduction into CO and formate are approaching industrial maturity, a current challenge is obtaining more reduced products like methanol. However, literature on the matter is scarce, and even more for the use of molecular catalysts. Here, we demonstrate that cobalt phthalocyanine, a well‐known catalyst for the electrochemical conversion of CO2 to CO, can also catalyze the reaction from CO2 or CO to methanol in aqueous electrolytes at ambient conditions of temperature and pressure. The studies identify formaldehyde as a key intermediate and an unexpected pH effect on selectivity. This paves the way for establishing a sequential process where CO2 is first converted to CO which is subsequently used as a reactant to produce methanol. Under ideal conditions, the reaction shows a global Faradaic efficiency of 19.5 % and chemical selectivity of 7.5 %. Abstract : Das Rad wird weitergedreht : Cobaltphthalocyanin, ein bekannter Katalysator für die elektrochemische Reduktion von CO2 zu CO, kann CO weiter zu Methanol in wässrigen Elektrolyten bei Standardbedingungen reduzieren. Formaldehyd ist dabei ein Intermediat auf dem Reaktionspfad. Unter optimierten Bedingungen kann CO2 in zwei elektrochemischen Schritten mit einem Faradayschen Wirkungsgrad von 19.5 % in Methanol umgewandelt werden.