Enhanced reaction kinetics of an aqueous Zn–Fe hybrid flow battery by optimizing the supporting electrolytes. (October 2019)

• Record Type: Journal Article
• Authors: Zhang, Yonglai; Henkensmeier, Dirk; Kim, Sangwon; Hempelmann, Rolf; Chen, Ruiyong
• Is Part Of: Journal of energy storage. Volume 25(2019)
• Publication Date: 2019-10
• Subjects: Redox flow battery -- Ionic liquid -- Iron species -- Zinc plating/stripping; Energy storage -- Periodicals; Energy storage -- Research -- Periodicals; 621.3126
• DOI: 10.1016/j.est.2019.100883
• Languages: English
• ISSNs: 2352-152X

Abstract

Highlights: Ionic liquid is introduced to regulate the redox behavior of iron species in the catholyte. Aqueous supporting electrolytes containing Cl - are utilized to study the reaction kinetics of zinc species in the anolyte. By using an anion exchange membrane, an aqueous Zn–Fe flow battery showed a high energy efficiency of 80% at 20 mA cm −2 . Abstract: Redox flow batteries attract ever growing interest over the past decades in stationary energy storage. Iron and zinc species have been widely studied as active species for redox flow batteries. In this paper, the redox behavior of iron species has been tested in aqueous ionic liquid solutions. 1-butyl-3-methylimidazolium chloride (BMImCl) is found to be most effective to regulate the redox activity of iron species. While in the anolyte, the standard rate constant of zinc plating/stripping can be promoted by one order up to 1.44 × 10 −4 cm s −1, when aqueous NH4 Cl is used as supporting electrolyte. Kinetic analysis is further conducted on the iron and zinc species in the corresponding supporting electrolytes. By using an anion exchange membrane, an aqueous Zn–Fe hybrid flow battery showed a high energy efficiency of 80% at 20 mA cm −2, making it an alternative for flow battery application.