High Capacitive Energy Storage of Nest‐Like Porous Graphene Microspheres Electrode with High Mass Loading. Issue 18 (13th August 2019)

• Record Type: Journal Article
• Authors: Wang, Xuejie; Song, Xinyu; Li, Shengping; Yu, Zhiqing; Zhao, Lu; Xiao, Zhihua; Zhang, Mengxuan; Xu, Chenggen; Qi, Chuanlei; Ma, Xinlong; Gao, Jinsen
• Is Part Of: ChemSusChem. Volume 12:Issue 18(2019)
• Page Start: 4249
• Page End: 4256
• Publication Date: 2019-08-13
• Subjects: capacitance -- chemical vapor deposition -- electrodes -- graphene -- supercapacitors; Green chemistry -- Periodicals; Sustainable engineering -- Periodicals; Chemistry -- Periodicals; Chemical engineering -- Periodicals; 660
• DOI: 10.1002/cssc.201901519
• Languages: English
• ISSNs: 1864-5631

Abstract

Abstract: Nest‐like porous graphene microspheres (NPGMs) are grown by using a chemical vapor deposition (CVD) method in a fluidized bed reactor from methane and basic magnesium carbonate microspheres (synthesized by a stirring‐induced crystallization approach) as carbon source and template, respectively. The CVD‐derived NPGMs have a few‐layer structure and high electrical conductivity, as well as a three‐dimensional individual macroarchitecture accompanied with well‐developed pore channels and great structural integrity. As the electrode for a symmetric supercapacitor, the effect of different mass loadings for NPGMs‐based electrodes on the capacitive energy‐storage performance is investigated. Superior electrochemical properties with respect to gravimetric, areal, and total capacitances, rate capability, and durability are shown by the NPGMs‐based symmetric supercapacitors, even at mass loadings up to 10 mg cm −2 . Moreover, the electrochemical behavior of the NPGMs‐based electrode is much superior to those of two‐dimensional lamella‐like graphene and commercial activated carbon. Abstract : Get loaded : Nest‐like porous graphene microspheres (NGPMs) are grown by a chemical vapor deposition method in a fluidized bed reactor from methane and basic magnesium carbonate microspheres as carbon source and template, respectively. As the electrode for a symmetric supercapacitor, NPGMs‐based electrodes show superior electrochemical properties with respect to capacitance, rate capability, and durability, even at mass loadings up to 10 mg cm −2 .