Enhanced interface reactivity by a nanowrinkled functional layer for intermediate-temperature solid oxide fuel cells. Issue 37 (15th August 2019)

• Record Type: Journal Article
• Authors: Lee, Jongseo; Hwang, Sangyeon; Ahn, Minwoo; Choi, Mingi; Han, Seungwoo; Byun, Doyoung; Lee, Wonyoung
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 37(2019)
• Page Start: 21120
• Page End: 21127
• Publication Date: 2019-08-15
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c9ta04818a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : For high-performance intermediate-temperature solid oxide fuel cells (IT-SOFCs), rational design of the interface between the electrode and electrolyte is essential, because interfacial reactivity often dominates the overall performance. Abstract : For high-performance intermediate-temperature solid oxide fuel cells (IT-SOFCs), rational design of the interface between the electrode and electrolyte is essential, because interfacial reactivity often dominates the overall performance. In this study, a unique nanowrinkled structure of a Gd0.1 Ce0.9 O1.95 functional layer is fabricated by electrostatic spray deposition (ESD) between a porous nanostructured electrode and dense electrolyte, for extended and activated reaction sites at the interfaces. Upon the introduction of the nanowrinkled functional layer, the polarization resistance is reduced 3.3-fold, while the peak power density is increased 2.2-fold (0.034 Ω cm 2 and 1.19 W cm −2, respectively) at 650 °C, compared to those of the reference sample. The substantial increases in surface area and grain boundary density in the nanowrinkled functional layer reduce both polarization resistance and activation energy, providing a significant performance enhancement. Our results demonstrate the importance of interface engineering with a cost-effective and simple ESD process to fully utilize the nanostructured electrodes for high-performance IT-SOFCs.