Large Electro‐Optic Kerr Effect in Ionic Liquid Crystals: Connecting Features of Liquid Crystals and Polyelectrolytes. Issue 18 (22nd June 2018)

• Record Type: Journal Article
• Authors: Schlick, M. Christian; Kapernaum, Nadia; Neidhardt, Manuel M.; Wöhrle, Tobias; Stöckl, Yannick; Laschat, Sabine; Giesselmann, Frank
• Is Part Of: Chemphyschem. Volume 19:Issue 18(2018)
• Page Start: 2305
• Page End: 2312
• Publication Date: 2018-06-22
• Subjects: Birefringence -- electro-optic Kerr effect -- ionic liquid crystals -- polyelectrolytes; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201800347
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract: The electro‐optic Kerr effect in simple dipolar fluids such as nitrobenzene has been widely applied in electro‐optical phase modulators and light shutters. In 2005, the discovery of the large Kerr effect in liquid‐crystalline blue phases (Y. Hisakado et al., Adv. Mater. 2005, 17, 96–98.) gave new directions to the search for advanced Kerr effect materials. Even though the Kerr effect is present in all transparent and optically isotropic media, it is well known that the effect can be anomalously large in complex fluids, namely in the isotropic phase of liquid crystals or in polyelectrolyte solutions. Herein, it is shown that the Kerr effect in the isotropic phase of ionic liquid crystals combines the effective counterion polarization mechanism found in polyelectrolytes and the unique pretransitional growth of the Kerr constant found in the isotropic phase of nematic liquid crystals. Maximum Kerr constants in the order of several 10 −11 m V −2 (ten times higher than the Kerr constant of the toxic nitrobenzene and less temperature sensitive than Kerr constants of nematic liquid crystals) make ionic liquid crystals attractive as new class of functional materials in low‐speed Kerr effect applications. Abstract : The Kerr effect in ionic liquid crystals is investigated in their isotropic phases and it is shown that the Kerr effect in these materials combines the effective counterion polarization mechanism found in polyelectrolytes and the unique pretransitional growth of the Kerr constant found in the isotropic phase of nematic liquid crystals. Ionic liquid crystals thus combine the Kerr effect features of liquid crystals and complex ionic fluids.