Hydrogen absorption by Ti-implanted Zr-1Nb alloy. (25th January 2018)

• Record Type: Journal Article
• Authors: Kashkarov, E.B.; Nikitenkov, N.N.; Sutygina, A.N.; Obrosov, A.; Manakhov, A.; Polčák, J.; Weiß, S.
• Is Part Of: International journal of hydrogen energy. Volume 43:Number 4(2018)
• Page Start: 2484
• Page End: 2491
• Publication Date: 2018-01-25
• Subjects: Zirconium -- Titanium implantation -- Hydrogenation -- X-ray photoelectron spectroscopy -- Glow discharge optical emission spectroscopy -- X-ray diffraction; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2017.12.003
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: This paper describes the hydrogenation behavior of Zr-1Nb alloy Ti-implanted by plasma immersion ion implantation (PIII). Hydrogen sorption kinetics of the Ti-modified alloy was investigated under gas-phase hydrogenation at 400 °C for 1 h. The influence of implantation time on the protective properties of the modified layer was shown. The lowest hydrogen absorption as well as the highest hydrogen trapping efficiency was achieved after PIII for 30 min. The main contribution to the reduction of hydrogen permeation is the formation of an oxide layer consisting of mixed TiO2 and ZrO2 on the modified surface of the alloy. X-ray photoelectron spectroscopy (XPS) revealed that PIII titanium oxide exists on the surface in the form of TiO2, which transforms to mixed Ti2 O3 and TiO2 after hydrogenation. The thickness of the modified layer increases with implantation time that improves the efficiency of hydrogen trapping. All the absorbed hydrogen is gradually distributed in the modified layer and no hydrides are formed after hydrogenation in Ti-modified Zr-1Nb for 15 and 30 min. Highlights: PIII positively effects on reduction of hydrogen absorption of Zr-1Nb alloy. Absorbed hydrogen preferably traps inside the Ti-modified layer. Thicker Ti-modified layer provides H trapping and reduction of H permeation. TiO2 and ZrO2 oxides formed on the surface plays a main role in H absorption kinetics. Oxygen deficient titanium oxides form after H interaction with TiO2 oxide layer.