Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil–Water Separation. (5th February 2019)

• Record Type: Journal Article
• Authors: Gu, Jiahui; Fan, Hongwei; Li, Chunxi; Caro, Jürgen; Meng, Hong
• Is Part Of: Angewandte Chemie. Volume 131:Number 16(2019)
• Page Start: 5351
• Page End: 5355
• Publication Date: 2019-02-05
• Subjects: Graphenbasierte Mikrokugeln -- Metallorganische Gerüste -- Öl-Wasser-Trennung -- Superhydrophobie -- Superoleophilität; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201814487
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Graphene/MOF‐based composite materials in three‐dimensional (3D) architectures are promising for the treatment of oil‐containing wastewater by absorption owing to their intrinsic properties of graphene and metal‐organic frameworks (MOFs), such as high porosity, ultralow density, and facilely tailored superwettability. In this study, novel wrinkled 3D microspherical MOF@rGO composites with both superhydrophobic and superoleophilic properties were developed by embedding MOF nanoparticles between graphene oxide (GO) nanosheets, followed by high‐temperature reduction self‐assembly. The microspherical composites feature a unique micro/nano hierarchy consisting of crumpled reduced GO (rGO) nanosheets intercalated with well‐dispersed MOF nanoparticles. Combined with the superwettability and abundant meso/microporosity, the peculiar architectures of wrinkled ZIF‐8@rGO microspheres show very fast absorption rates and high sorption selectivity for organic solvents and oils from water.