Exploiting Boron Coordination: B←N Bond Supports a [2+2] Photodimerization in the Solid State and Generation of a Diboron Bis‐Tweezer for Benzene/Thiophene Separation. (12th March 2019)
- Record Type:
- Journal Article
- Title:
- Exploiting Boron Coordination: B←N Bond Supports a [2+2] Photodimerization in the Solid State and Generation of a Diboron Bis‐Tweezer for Benzene/Thiophene Separation. (12th March 2019)
- Main Title:
- Exploiting Boron Coordination: B←N Bond Supports a [2+2] Photodimerization in the Solid State and Generation of a Diboron Bis‐Tweezer for Benzene/Thiophene Separation
- Authors:
- Campillo‐Alvarado, Gonzalo
D'mello, Kyle P.
Swenson, Dale C.
Santhana Mariappan, S. V.
Höpfl, Herbert
Morales‐Rojas, Hugo
MacGillivray, Leonard R. - Abstract:
- Abstract: B←N coordination supports a [2+2] photodimerization in the solid state. The bond is defined by an orthogonal interaction between stilbazole and a phenylboronic ester to enable a stereocontrolled and rapid photoreaction. The cyclobutane photoproduct affords a novel diboron bis‐tweezer adduct that is used to separate a mixture of benzene and thiophene upon crystallization.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 16(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 16(2019)
- Issue Display:
- Volume 131, Issue 16 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 16
- Issue Sort Value:
- 2019-0131-0016-0000
- Page Start:
- 5467
- Page End:
- 5470
- Publication Date:
- 2019-03-12
- Subjects:
- Borester -- Bor-Stickstoff-Addukte -- Dimerisierung -- Molekulare Erkennung -- Selbstassemblierung
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201812174 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11771.xml