Reversible Hydrogen Uptake/Release over a Sodium Phenoxide–Cyclohexanolate Pair. (17th December 2018)

• Record Type: Journal Article
• Authors: Yu, Yang; He, Teng; Wu, Anan; Pei, Qijun; Karkamkar, Abhijeet; Autrey, Tom; Chen, Ping
• Is Part Of: Angewandte Chemie. Volume 131:Number 10(2019)
• Page Start: 3134
• Page End: 3139
• Publication Date: 2018-12-17
• Subjects: Metallierungen -- Organische Hydride -- Thermodynamische Modifikation -- Wasserstoffspeicher; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201810945
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Hydrogen uptake and release in arene–cycloalkane pairs provide an attractive opportunity for on‐board and off‐board hydrogen storage. However, the efficiency of arene–cycloalkane pairs currently is limited by unfavorable thermodynamics for hydrogen release. It is shown here that the thermodynamics can be optimized by replacement of H in the ‐OH group of cyclohexanol and phenol with alkali or alkaline earth metals. The enthalpy change upon dehydrogenation decreases substantially, which correlates with the delocalization of the oxygen electron to the benzene ring in phenoxides. Theoretical calculations reveal that replacement of H with a metal leads to a reduction of the HOMO–LUMO energy gap and elongation of the C−H bond in the α site in cyclohexanolate, which indicates that the cyclohexanol is activated upon metal substitution. The experimental results demonstrate that sodium phenoxide–cyclohexanolate, an air‐ and water‐stable pair, can desorb hydrogen at ca. 413 K and 373 K in the solid form and in an aqueous solution, respectively. Hydrogenation, on the other hand, is accomplished at temperatures as low as 303 K.