Dearomatization of 3‐Nitroindoles by a Phosphine‐Catalyzed Enantioselective [3+2] Annulation Reaction. (18th March 2019)
- Record Type:
- Journal Article
- Title:
- Dearomatization of 3‐Nitroindoles by a Phosphine‐Catalyzed Enantioselective [3+2] Annulation Reaction. (18th March 2019)
- Main Title:
- Dearomatization of 3‐Nitroindoles by a Phosphine‐Catalyzed Enantioselective [3+2] Annulation Reaction
- Authors:
- Li, Kaizhi
Gonçalves, Théo P.
Huang, Kuo‐Wei
Lu, Yixin - Abstract:
- Abstract: The dearomatization of 3‐nitroindoles through a chiral‐phosphine‐mediated [3+2] annulation reaction is described. This method makes use of readily available 3‐nitroindoles as an aromatic feedstock and rapidly delivers a wide range of cyclopentaindoline alkaloid scaffolds in a highly enantioselective manner. Notably, phosphine‐triggered cyclization has not been utilized previously in a dearomatization process.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 16(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 16(2019)
- Issue Display:
- Volume 131, Issue 16 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 16
- Issue Sort Value:
- 2019-0131-0016-0000
- Page Start:
- 5481
- Page End:
- 5485
- Publication Date:
- 2019-03-18
- Subjects:
- [3+2]-Anellierung -- Cyclopentaindoline -- Dearomatisierung -- Nitroindole -- Organokatalyse
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201900248 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11746.xml