Advanced anti-corrosion coatings prepared from α-zirconium phosphate/polyurethane nanocomposites. Issue 16 (3rd February 2017)

• Record Type: Journal Article
• Authors: Huang, Tsao-Cheng; Lai, Guan-Hui; Li, Chen-En; Tsai, Mei-Hui; Wan, Peng-Yun; Chung, Yi-Hsiu; Lin, Meng-Hung
• Is Part Of: RSC advances. Volume 7:Issue 16(2017)
• Page Start: 9908
• Page End: 9913
• Publication Date: 2017-02-03
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra27588e
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : This paper presents the first successful application of α-zirconium phosphate/polyurethane (ZrP/PU) nanocomposites for corrosion protection. Abstract : This paper presents the first successful application of α-zirconium phosphate/polyurethane (ZrP/PU) nanocomposites for corrosion protection. ZrP nanoplatelets were synthesized using a reflux method and modified with a polyetheramine surfactant (Jeffamine M1000) to form organic ZrP nanoplatelets. ZrP/PU nanocomposite films were based on PU and ZrP with different ZrP contents from 0.5–5 wt%. To probe the internal morphology of ZrP/PU nanocomposites, their cross-sections were examined by scanning and transmission electron microscopy. The results reveal that ZrP dispersed very well in PU films and that no substantial agglomeration occurred. Well-dispersed ZrP nanoplatelets in a PU matrix could effectively enhance the moisture barrier properties of ZrP/PU films. The water vapor transmission rate was significantly reduced to 84 g m −2 per day for ZrP/PU films compared to 194 g m −2 per day for pure PU films. Using a series of electrochemical measurements of corrosion potential ( E corr ), polarization resistance ( R p ), corrosion current ( I corr ), and electrochemical impedance spectroscopy, ZrP/PU coatings on cold-rolled steel electrodes were also found to exhibit enhanced corrosion protection properties compared to pure PU coatings.