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Direct synthesis of N-sulfinyl- and N-sulfonylimines via copper/l-proline-catalyzed aerobic oxidative cascade reaction of alcohols with sulfinamides or sulfonamides. Issue 16 (30th January 2017)
Record Type:
Journal Article
Title:
Direct synthesis of N-sulfinyl- and N-sulfonylimines via copper/l-proline-catalyzed aerobic oxidative cascade reaction of alcohols with sulfinamides or sulfonamides. Issue 16 (30th January 2017)
Main Title:
Direct synthesis of N-sulfinyl- and N-sulfonylimines via copper/l-proline-catalyzed aerobic oxidative cascade reaction of alcohols with sulfinamides or sulfonamides
Abstract : An efficient one-pot synthesis of N -sulfinyl- and N -sulfonylimines directly from alcohols with sulfinamides or sulfonamides. Abstract : An efficient one-pot synthetic method of N -sulfinyl- and N -sulfonylimines by the condensation of alcohols with sulfinamides or sulfonamides under mild and green conditions has been developed using a combination of CuI, l -proline and TEMPO. This system shows excellent functional group compatibility for a wide range of substrates and affords the corresponding products in good to excellent yields.