Effect of ultraviolet‐A radiation on surface structure, thermal, and mechanical and electrical properties of liquid silicone rubber. Issue 24 (22nd February 2019)

• Record Type: Journal Article
• Authors: Lin, Ying; Yin, Fanghui; Liu, Yuhao; Wang, Liming; Zhao, Yunfeng; Farzaneh, Masoud
• Is Part Of: Journal of applied polymer science. Volume 136:Issue 24(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-02-22
• Subjects: degradation mechanisms -- liquid silicone rubber -- mechanical and electrical properties -- surface structure -- ultraviolet‐A radiation; Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.47652
• Languages: English
• ISSNs: 0021-8995

Abstract

ABSTRACT: Liquid silicone rubber (LSR) products outdoors are often subjected to high intensity of ultraviolet (UV)‐A radiation. However, the influence of UV‐A radiation on LSR is rarely studied. To study the influence of UV‐A radiation on LSR, the surface of LSR with UV‐A aging time was characterized by tests at different detection depths [X‐ray photoelectron spectroscopy (XPS), energy dispersive X‐ray spectroscopy (EDS), and Fourier transform infrared spectroscopy (FTIR)]. The operation properties (thermal stability and mechanical and electrical properties) for outdoor insulators were also analyzed. It was found that the porous surface and the loose layer of LSR increased, but the growth rate of them decreased as UV‐A aging time increased. SiO2 fillers were lost in the surface. CH bonds in CH3 and CH3 in SiCH3 increased with aging time. The increased crosslinking density increased the thermal stability, hardness, dielectric loss tangent, relative dielectric constant, and volume resistivity and decreased elongation‐at‐break. The mechanical strength initially increased and then decreased. Based on the proposed aging mechanism, the UV‐A resistance of LSR can be improved by reducing the amount of hydrogen‐containing silicone oil and by increasing the molecular weight of raw rubber. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2019, 136, 47652. Abstract :