One- and two-photon absorption properties of quadrupolar thiophene-based dyes with acceptors of varying strengths. Issue 9 (28th February 2019)

• Record Type: Journal Article
• Authors: Canola, Sofia; Mardegan, Lorenzo; Bergamini, Giacomo; Villa, Marco; Acocella, Angela; Zangoli, Mattia; Ravotto, Luca; Vinogradov, Sergei A.; Di Maria, Francesca; Ceroni, Paola; Negri, Fabrizia
• Is Part Of: Photochemical & photobiological sciences. Volume 18:Issue 9(2019)
• Page Start: 2180
• Page End: 2190
• Publication Date: 2019-02-28
• Subjects: Photochemistry -- Periodicals; Photobiology -- Periodicals; 541.35
• DOI: 10.1039/c9pp00006b
• Languages: English
• ISSNs: 1474-905X

Abstract

Abstract : The effect of acceptors of varying strengths on the 1P and 2P properties of DAD thiophene based dyes is determined by a combination of experimental and computational methods. Abstract : The one-photon (1P) and two-photon (2P) absorption properties of three quadrupolar dyes, featuring thiophene as a donor and acceptors of varying strengths, are determined by a combination of experimental and computational methods employing the density functional theory (DFT). The emission shifts in different solvents are well reproduced by time-dependent DFT calculations with the linear response and state specific approaches in the framework of the polarizable continuum model. The calculations show that the energies of both 1P- and 2P-active states decrease with an increase of the strength of the acceptor. The 2P absorption cross-sections predicted by the response theory are accounted for by considering just one intermediate state (S1 ) in the sum-over-states formulation. For the chromophore featuring the stronger acceptor, the energetic positions of the 1P- and 2P-active states prevent the exploitation of the theoretically predicted very high 2P activity due to the competing 1P absorption into the S1 state.