One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion. Issue 35 (6th August 2019)

• Record Type: Journal Article
• Authors: Isoda, Kyosuke; Takahashi, Hinako; Mutoh, Yuichiro; Hoshino, Norihisa; Akutagawa, Tomoyuki
• Is Part Of: Dalton transactions. Volume 48:Issue 35(2019)
• Page Start: 13125
• Page End: 13129
• Publication Date: 2019-08-06
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt02797a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Radical anions based on crown-ether appended N-heteroacene with Na + self-assemble one-dimensional helical coordination polymers. Abstract : A crown-ether appended N-heteroacene1 was reduced in the presence of NaBPh4 to the radical anion2 by accepting one electron transferred from both the cathode and BPh4 – as a reductant. The obtained radical anion2 can function as a radical anion ligand to bridge two sodium ions to self-assemble into one-dimensional helical coordination polymers.