BaMnSnS4 and BaCdGeS4: infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity12. Issue 9 (30th July 2019)

• Record Type: Journal Article
• Authors: Lin, Yang-Jie; Ye, Run; Yang, Long-Qi; Jiang, Xiao-Ming; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong
• Is Part Of: Inorganic chemistry frontiers. Volume 6:Issue 9(2019)
• Page Start: 2365
• Page End: 2368
• Publication Date: 2019-07-30
• Subjects: Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9qi00727j
• Languages: English
• ISSNs: 2052-1553

Abstract

Abstract : IR NLO sulfides BaMnSnS4 and BaCdGeS4 exhibit significant SHG efficiencies (1.2 and 0.3AgGaS2 ) with phase-matching behavior and high laser-induced damage thresholds (10 and 13AgGaS2 ). Abstract : IR NLO sulfides BaMnSnS4 and BaCdGeS4 exhibit significant SHG efficiencies (1.2 and 0.3AgGaS2 ) with phase-matching behavior and high laser-induced damage thresholds (10 and 13AgGaS2 ). Their strong SHG efficiencies mainly originate from SnS4 and GeS4 tetrahedra that are being modulated by highly distorted MnS4 and CdS4 tetrahedra.