Investigation of Fe−Ni Mixed‐Oxide Catalysts for the Reduction of NO by CO: Physicochemical Properties and Catalytic Performance. Issue 17 (1st August 2019)

• Record Type: Journal Article
• Authors: Du, Xuexun; Yao, Tian‐Liang; Wei, Qinglian; Zhang, Hao; Huang, Yongmin
• Is Part Of: Chemistry, an Asian journal. Volume 14:Issue 17(2019)
• Page Start: 2966
• Page End: 2978
• Publication Date: 2019-08-01
• Subjects: carbon monoxide -- nitric oxide -- reaction mechanisms -- reduction -- synthetic methods; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201900782
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: A series of Fe−Ni mixed‐oxide catalysts were synthesized by using the sol–gel method for the reduction of NO by CO. These Fe−Ni mixed‐oxide catalysts exhibited tremendously enhanced catalytic performance compared to monometallic catalysts that were prepared by using the same method. The effects of Fe/Ni molar ratio and calcination temperature on the catalytic activity were examined and the physicochemical properties of the catalysts were characterized by using XRD, Raman spectroscopy, N2 ‐adsorption/‐desorption isotherms, temperature‐programmed reduction with hydrogen (H2 ‐TPR), temperature‐programmed desorption of nitric oxide (NO‐TPD), and X‐ray photoelectron spectroscopy (XPS). The results indicated that the reduction behavior, surface oxygen species, and surface chemical valence states of iron and nickel in the catalysts were the key factors in the NO elimination. Fe0.5 Ni0.5 O x that was calcined at 250 °C exhibited excellent catalytic activity of 100 % NO conversion at 130 °C and a lifetime of more than 40 hours. A plausible mechanism for the reduction of NO by CO over the Fe−Ni mixed‐oxide catalysts is proposed, based on XPS and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analyses. Abstract : Reduced to clear : Fe−Ni mixed‐oxide catalysts showed excellent catalytic performance for the reduction of NO by CO at low temperatures. The correlation between the physicochemical properties of the catalysts and their catalytic performance was investigated and a possible mechanism is proposed.