Poly(ethylene glycol) nanocomposites of sub-nanometer metal oxide clusters for dynamic semi-solid proton conductive electrolytes. Issue 31 (19th July 2019)

• Record Type: Journal Article
• Authors: Zheng, Zhao; Zhou, Qianjie; Li, Mu; Yin, Panchao
• Is Part Of: Chemical science. Volume 10:Issue 31(2019)
• Page Start: 7333
• Page End: 7339
• Publication Date: 2019-07-19
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c9sc02779c
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : PEG–POM nanocomposites are ideal candidates for semi-solid proton conductors with high proton conductivities and devisable mechanical performances. Abstract : Sub-nm-scale metal oxide clusters (PW12 O40 3− ) show high solubility in the melt of poly(ethylene glycol) (PEG) and the obtained semi-solid nanocomposites show promising proton conductivities under ambient conditions. Suggested from scattering studies, the clusters are homogeneously dispersed in the PEG melt at the molecular scale with high loading amounts (70 wt%) and the formed real solutions can be stable for months with no aggregation or phase separation. The conductivities of the nanocomposites which are governed by the concentrations of H3 PW12 O40 can reach as high as 1.01 × 10 −2 S cm −1 at the highest concentration. Due to the dynamic cross-linking hydrogen bonding between clusters and PEG, the nanocomposites behave like solids with negligible flow at high concentrations of clusters. Upon the application of high-speed shear forces (>32 s −1 ), the composites can flow with continuously decreasing viscosities. The shear thinning properties of the nanocomposites enable their convenient processing into required morphologies and the wettability of electrolytes to electrodes under typical high shear rate processing conditions and the safety of the produced devices can be ensured by their solid-like properties in the static state.