Palladium-catalyzed carbene/alkyne metathesis with enynones as carbene precursors: synthesis of fused polyheterocycles. Issue 4 (13th December 2017)
- Record Type:
- Journal Article
- Title:
- Palladium-catalyzed carbene/alkyne metathesis with enynones as carbene precursors: synthesis of fused polyheterocycles. Issue 4 (13th December 2017)
- Main Title:
- Palladium-catalyzed carbene/alkyne metathesis with enynones as carbene precursors: synthesis of fused polyheterocycles
- Authors:
- Zheng, Yang
Bao, Ming
Yao, Ruwei
Qiu, Lihua
Xu, Xinfang - Abstract:
- Abstract : An unprecedented palladium-catalyzed carbene/alkyne metathesis reaction of alkyne-tethered enynones is described, which delivers fused-furans in moderate to good yields. Abstract : An unprecedented palladium-catalyzed novel carbene/alkyne metathesis cascade reaction of alkyne-tethered enynones is described. This reaction affords fused polyheterocycles in moderate to good yields. The transformation begins with Pd-catalyzed 5- exo -dig cyclization of the enynone to form the donor/donor metal carbene, which then undergoes metathesis with the alkyne followed by electrophilic aromatic substitution.
- Is Part Of:
- Chemical communications. Volume 54:Issue 4(2018)
- Journal:
- Chemical communications
- Issue:
- Volume 54:Issue 4(2018)
- Issue Display:
- Volume 54, Issue 4 (2018)
- Year:
- 2018
- Volume:
- 54
- Issue:
- 4
- Issue Sort Value:
- 2018-0054-0004-0000
- Page Start:
- 350
- Page End:
- 353
- Publication Date:
- 2017-12-13
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc08221e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 11618.xml