Alkene 1, 2‐Difunctionalization by Radical Alkenyl Migration. (14th December 2017)
- Record Type:
- Journal Article
- Title:
- Alkene 1, 2‐Difunctionalization by Radical Alkenyl Migration. (14th December 2017)
- Main Title:
- Alkene 1, 2‐Difunctionalization by Radical Alkenyl Migration
- Authors:
- Tang, Xinjun
Studer, Armido - Abstract:
- Abstract: Transition‐metal‐free radical α‐perfluoroalkylation with the accompanying vicinal β‐alkenylation of unactivated alkenes is presented. These radical cascades proceed by means of 1, 4‐ or 1, 5‐alkenyl migration by electron catalysis on readily accessed allylic alcohols. The reactions comprise a regioselective perfluoroalkyl radical addition with subsequent alkenyl migration and concomitant deprotonation to generate a ketyl radical anion that sustains the chain as a single‐electron‐transfer reducing reagent.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 3(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 3(2018)
- Issue Display:
- Volume 130, Issue 3 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 3
- Issue Sort Value:
- 2018-0130-0003-0000
- Page Start:
- 822
- Page End:
- 825
- Publication Date:
- 2017-12-14
- Subjects:
- Alkene -- Alkenylverschiebungen -- Alkenylierungen -- Perfluoralkylierungen -- Einelektrontransfer
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201710397 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 11607.xml